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 Pure Appl. Chem. Vol. 67, No. 5 (1995)

Pure and Applied Chemistry

Vol. 67, Issue 5


12th International Conference on Physical Organic Chemistry

IUPAC Recommendations on Nomenclature and Symbols and Technical Reports from Commissions



12th International Conference on Physical Organic Chemistry, Padua, Italy, 28 August-2 September 1994

Preface
R. Curci and G. Scorrano
p. iv [full text - pdf 402 kB]

C. K. Ingold: A chemical revolutionary
C. A. Bunton
p. 667 [full text - pdf 470 kB]

Cyclic electron delocalization in hydrocarbon cages: Pagodanes, isopagodanes, (bisseco/seco-)dodecahedradienes
H. Prinzbach, G. Gescheidt, H.-D. Martin, R . Herges, J. Heinze, G. K. Surya Prakash and G. A. Olah
p. 673 [full text - pdf 676 kB]

Interaction between stacked aryl groups in 1,8-diarylnaphthalenes: Dominance of polar/p over charge-transfer effects
F. Cozzi and J. S. Siegel
p. 683 [full text - pdf 457 kB]

Enantiomeric recognition of chiral ammonium salts by chiral pyridino- and pyrimidino-18-crown-6 ligands: Effect of structure and solvents
J. S. Bradshaw, P. Huszthy, J. Ty Redd, X.-X. Zhang, T.-M. Wang, J. K. Hathaway, J. Young and R . M. Izatt
p. 691 [full text - pdf 340 kB]

Anion activation by quaternary onium salts and polyether ligands in homogeneous and heterogeneous systems
A. Maia
p. 697 [full text - pdf 396 kB]

Reductively activated 'polar' nucleophilic aromatic substitution. A new mechanism in aromatic chemistry?
J. Marquet, F. Casado, M. Cervera, M. Espin, I. Gallardo, M. Mir and M. Niat
p. 703 [full text - pdf 548 kB]

Reactivity of b-lactams and phosphonamidates and reactions with b-lactamase
M. I. Page, A. P. Laws, M. J. Slater and J. R. Stone
p. 711 [full text - pdf 597 kB]

Reverse anomeric effect and steric hindrance to solvation of ionic groups
C. L. Perrin
p. 719 [full text - pdf 911 kB]

Thermodynamics for C-H bond-breaking of some amphihydric compounds by transfer of protons, hydride ions, H-atoms and electrons
E. M. Arnett, R. A. Flowers II, R. T. Ludwig, A. Meekhof and S. Walek
p. 729 [full text - pdf 556 kB]

Using thermodynamic cycles to study reactive intermediates
F. G. Bordwell, A. V. Satish, S. Zhang and X.-M. Zhang
p. 735 [full text - pdf 437 kB]

Dynamics of intramolecular carbenic rearrangements
R. A. Moss
p. 741 [full text - pdf 581 kB]

The use of 1,2-shifts in carbenes and nitrenes in the generation of novel heterocumulenes
C. Wentrup, C. O. Kappe and M. W. Wong
p. 749 [full text - pdf 355 kB]

Exact structures of carbocations established by combined computational and experimental methods
P. von Rague Schleyer and C. Maerker
p. 755 [full text - pdf 378 kB]

Matrix isolation and vibrational spectroscopy of carbocations
H. Vancik
p. 761 [full text - pdf 473 kB]

NMR spectroscopic and computational investigations of s-interactions in carbocations: The b-silyl effect in vinyl cations
H.-U. Siehl
p. 769 [full text - pdf 349 kB]

Silylated bisketenes: Accessible and reactive organic intermediates
A. D. Allen, R. Liu, J. Ma, M. A. McAllister, T. T. Tidwell and D.-c. Zhao
p. 777 [full text - pdf 338 kB]

Conical intersections as a mechanistic feature of organic photochemistry
M. A. Robb, F. Bernardi and M. Olivucci
p. 783 [full text - pdf 519 kB]

Thornton rule for homolytic reactions
S. S. Kim
p. 791 [full text - pdf 291 kB]

MO study of the effect of substituents on the properties of localized organic and organometallic radicals
M. Guerra
p. 797 [full text - pdf 482 kB]

Highly reactive small and medium carbacyclic silanes and germanes
W. Ando
p. 805 [full text - pdf 302 kB]

Dioxirane oxidations: Taming the reactivity-selectivity principle
R. Curci, A. Dinoi and M. F. Rubino
p. 811 [full text - pdf 817 kB]

Diels-Alder reactions in water: Enforced hydrophobic interaction and hydrogen bonding
J. B. F. N. Engberts
p. 823 [full text - pdf 402 kB]

Dextran modified self-assembled monolayer surfaces for use in biointeraction analysis with surface plasmon resonance
S. Lofas
p. 829 [full text - pdf 638 kB]

The centenary of the birth of Louis Hammett
J. Shorter
p. 835 [full text - pdf 793 kB]

IUPAC Recommendations on Nomenclature and Symbols and Technical Reports from Commissions

Some problems in the destruction of chemical munitions, and recommendations toward their amelioration (Technical Report)
Task Force on Scientific Aspects of the Destruction of Chemical Warfare Agents
J. F. Bunnett
p. 841 [full text - pdf 1350 kB]


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